Information card for entry 7008801

Structure parameters

• Formula: C22 H60 Li4 O7 Si6
• Calculated formula: C22 H60 Li4 O7 Si6
• SMILES: [Li]12[C@H]([Si](C)(C)C)[Si]3([O]([Li]4[O]([Si]([O]([Li]5[O]([Si]([O]([Li]([O]3C)[O]45C)C)([C@H]1[Si](C)(C)C)C)C)C)([C@H]2[Si](C)(C)C)C)C)C)C.[Li]12[C@@H]([Si](C)(C)C)[Si]3([O]([Li]4[O]([Si]([O]([Li]5[O]([Si]([O]([Li]([O]3C)[O]45C)C)([C@@H]1[Si](C)(C)C)C)C)C)([C@@H]2[Si](C)(C)C)C)C)C)C
• Title of publication: The coordination chemistry of the C1-symmetric bis(silyl)methyl ligand [CH(SiMe3){SiMe(OMe)2}]- revisited: Li/M- (M = Zn, Tl, Ce), Li4- or Ce2-methoxy-bridged alkyls.
• Authors of publication: Hitchcock, Peter B.; Huang, Qigu; Lappert, Michael F.; Zhou, Meisu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 18
• Pages of publication: 2988 - 2993
• a: 10.0199 ± 0.0001 Å
• b: 22.1861 ± 0.0004 Å
• c: 18.1958 ± 0.0004 Å
• α: 90°
• β: 99.023 ± 0.001°
• γ: 90°
• Cell volume: 3994.92 ± 0.12 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0664
• Residual factor for significantly intense reflections: 0.0572
• Weighted residual factors for significantly intense reflections: 0.1441
• Weighted residual factors for all reflections included in the refinement: 0.152
• Goodness-of-fit parameter for all reflections included in the refinement: 1.098
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No