Information card for entry 7011473

Structure parameters

• Formula: C32 H34 Cl2 N2 P Rh
• Calculated formula: C32 H34 Cl2 N2 P Rh
• SMILES: [Rh]1234(Cl)(Cl)([P](c5ccccc5)(c5ccccc5)CNc5c6c(ccc5)cccn6)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Co-ordination chemistry and metal catalysed carbonylation reactions using 8-(diphenylphosphino)methylaminoquinoline: a ligand that displays monodentate, bidentate and tridentate co-ordination modes
• Authors of publication: Matthew L. Clarke; David J. Cole-Hamilton; Douglas F. Foster; Alexandra M. Z. Slawin; J. Derek Woollins
• Journal of publication: J. Chem. Soc., Dalton Trans.
• Year of publication: 2002
• Journal issue: 8
• Pages of publication: 1618 - 1624
• a: 21.779 ± 0.002 Å
• b: 8.4708 ± 0.0008 Å
• c: 16.3038 ± 0.0015 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3007.8 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0765
• Residual factor for significantly intense reflections: 0.0388
• Weighted residual factors for significantly intense reflections: 0.0743
• Weighted residual factors for all reflections included in the refinement: 0.0865
• Goodness-of-fit parameter for all reflections included in the refinement: 0.912
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No