Information card for entry 7011474

Structure parameters

• Formula: C24 H23 F6 N6 O14 P Ru2
• Calculated formula: C24 H21 F6 N6 O14 P Ru2
• SMILES: [Ru]12([OH2])(OC(=O)c3[n]1cccc3)(OC(=O)c1[n]2cccc1)N=O.O[Ru]34(OC(=O)c5[n]3cccc5)(OC(=O)c3[n]4cccc3)N=O.[P](F)(F)(F)(F)(F)[F-].O.O
• Title of publication: Cis‒trans isomerization of {RuNO}6-type nitrosylruthenium complexes containing 2-pyridinecarboxylate and structural characterization of a µ-H3O2 bridged dinuclear nitrosylruthenium complex
• Authors of publication: Hirano, Toshiyuki; Kuroda, Mai; Takeda, Naoko; Hayashi, Mitsunori; Mukaida, Masao; Oi, Takao; Nagao, Hirotaka
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 10
• Pages of publication: 2158
• a: 11.7164 ± 0.0002 Å
• b: 13.5928 ± 0.0002 Å
• c: 21.0368 ± 0.0004 Å
• α: 90°
• β: 99.75 ± 0.001°
• γ: 90°
• Cell volume: 3301.9 ± 0.1 ų
• Ambient diffraction temperature: 123.2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0289
• Weighted residual factors for all reflections included in the refinement: 0.0364
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No