Information card for entry 7012458

Structure parameters

• Formula: C34 H68 As Li N2 O P4
• Calculated formula: C34 H68 As Li N2 O P4
• Title of publication: Reactions of metallated cyclohexyl phosphine (CyPHM) with As(NMe2)3; synthesis of [(CyP)4As]‒ anions (M = Li or Na, Cy = cyclohexyl)
• Authors of publication: Bashall, Alan; García, Felipe; Hopkins, Alexander A.; Wood, Jody A.; McPartlin, Mary; Woods, Anthony D.; Wright, Dominic S.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 6
• Pages of publication: 1143
• a: 19.204 ± 0.004 Å
• b: 19.464 ± 0.006 Å
• c: 21.771 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8138 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.2643
• Residual factor for significantly intense reflections: 0.0822
• Weighted residual factors for significantly intense reflections: 0.1127
• Weighted residual factors for all reflections included in the refinement: 0.1438
• Goodness-of-fit parameter for all reflections included in the refinement: 0.835
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No