Information card for entry 7012459

Structure parameters

• Formula: C30 H65 As Li N3 P4
• Calculated formula: C30 H65 As Li N3 P4
• SMILES: [As]1(P(P(P(P1C1CCCCC1)C1CCCCC1)C1CCCCC1)C1CCCCC1)[Li]([NH](C)C)([NH](C)C)[NH](C)C
• Title of publication: Reactions of metallated cyclohexyl phosphine (CyPHM) with As(NMe2)3; synthesis of [(CyP)4As]‒ anions (M = Li or Na, Cy = cyclohexyl)
• Authors of publication: Bashall, Alan; García, Felipe; Hopkins, Alexander A.; Wood, Jody A.; McPartlin, Mary; Woods, Anthony D.; Wright, Dominic S.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 6
• Pages of publication: 1143
• a: 10.2635 ± 0.0003 Å
• b: 15.4835 ± 0.0005 Å
• c: 24.322 ± 0.0004 Å
• α: 90°
• β: 96.165 ± 0.002°
• γ: 90°
• Cell volume: 3842.78 ± 0.18 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0785
• Residual factor for significantly intense reflections: 0.0404
• Weighted residual factors for significantly intense reflections: 0.0736
• Weighted residual factors for all reflections included in the refinement: 0.0831
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No