Information card for entry 7012460

Structure parameters

• Formula: C30 H60 As N2 Na P4
• Calculated formula: C30 H60 As N2 Na P4
• SMILES: [As-]1(P(P(P(P1C1CCCCC1)C1CCCCC1)C1CCCCC1)C1CCCCC1).[Na]1[N](C)(C)CC[N]1(C)C
• Title of publication: Reactions of metallated cyclohexyl phosphine (CyPHM) with As(NMe2)3; synthesis of [(CyP)4As]‒ anions (M = Li or Na, Cy = cyclohexyl)
• Authors of publication: Bashall, Alan; García, Felipe; Hopkins, Alexander A.; Wood, Jody A.; McPartlin, Mary; Woods, Anthony D.; Wright, Dominic S.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 6
• Pages of publication: 1143
• a: 10.8971 ± 0.0003 Å
• b: 17.5762 ± 0.0006 Å
• c: 19.5359 ± 0.0007 Å
• α: 90°
• β: 92.037 ± 0.002°
• γ: 90°
• Cell volume: 3739.3 ± 0.2 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0651
• Residual factor for significantly intense reflections: 0.0387
• Weighted residual factors for all reflections: 0.1682
• Weighted residual factors for significantly intense reflections: 0.0706
• Goodness-of-fit parameter for all reflections: 1.022
• Goodness-of-fit parameter for significantly intense reflections: 1.065
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No