Information card for entry 7013113

Structure parameters

• Formula: C44 H98 N2 O8 Si W2
• Calculated formula: C44 H98 N2 O8 Si W2
• SMILES: [W]123([W]([O]1CC(C)(C)C)([O]2CC(C)(C)C)(OCC(C)(C)C)(OCC(C)(C)C)(OCC(C)(C)C)N3/N=C/[Si](C)(C)C)(OCC(C)(C)C)(OCC(C)(C)C)OCC(C)(C)C
• Title of publication: Reactions of [W2(OCH2tBu)8] (M?M) with diazobenzene and trimethylsilyldiazomethane. Preparation and structures of W2(OCH2tBu)8(NPh) and W2(OCH2tBu)8(N2C(H)SiMe3)
• Authors of publication: Chisholm, Malcolm H.; Click, Damon R.; Gallucci, Judith C.; Hadad, Christopher M.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 16
• Pages of publication: 3205
• a: 11.921 ± 0.001 Å
• b: 11.954 ± 0.001 Å
• c: 21.526 ± 0.002 Å
• α: 88.91 ± 0.01°
• β: 85 ± 0.01°
• γ: 74.92 ± 0.01°
• Cell volume: 2950.6 ± 0.5 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0421
• Residual factor for significantly intense reflections: 0.0263
• Weighted residual factors for all reflections: 0.0621
• Weighted residual factors for significantly intense reflections: 0.0578
• Goodness-of-fit parameter for all reflections: 1.034
• Goodness-of-fit parameter for significantly intense reflections: 1.086
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No