Information card for entry 7013114

Structure parameters

• Formula: C49 H100 N O8 W2
• Calculated formula: C49 H97 N O8 W2
• Title of publication: Reactions of [W2(OCH2tBu)8] (M?M) with diazobenzene and trimethylsilyldiazomethane. Preparation and structures of W2(OCH2tBu)8(NPh) and W2(OCH2tBu)8(N2C(H)SiMe3)
• Authors of publication: Chisholm, Malcolm H.; Click, Damon R.; Gallucci, Judith C.; Hadad, Christopher M.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 16
• Pages of publication: 3205
• a: 12.03 ± 0.001 Å
• b: 12.048 ± 0.001 Å
• c: 20.567 ± 0.002 Å
• α: 92.84 ± 0.01°
• β: 99.67 ± 0.01°
• γ: 102.96 ± 0.01°
• Cell volume: 2851.9 ± 0.5 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0295
• Weighted residual factors for all reflections: 0.0613
• Weighted residual factors for significantly intense reflections: 0.0569
• Goodness-of-fit parameter for all reflections: 1.092
• Goodness-of-fit parameter for significantly intense reflections: 1.148
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No