Information card for entry 7013284

Structure parameters

• Formula: C63 H49 Co4 O11 P5
• Calculated formula: C63 H49 Co4 O11 P5
• SMILES: [Co]123([Co]4([P](OC)(OC)OC)(C#[O])(C#[O])[C]52[P]([Co]26([Co]7([P]([C]34=5)(c3ccccc3)c3ccccc3)(C#[O])(C#[O])[C]2([P]1(c1ccccc1)c1ccccc1)=[C]67[P](c1ccccc1)c1ccccc1)(C#[O])C#[O])(c1ccccc1)c1ccccc1)(C#[O])C#[O]
• Title of publication: Synthesis and structural characterization of novel palladium complexes chelated by bulky cobalt-containing phosphine ligands: unusual palladium?cobalt bond formation
• Authors of publication: Hong, Fung-E; Chang, Chin-Pei; Chang, Yu-Chang
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 20
• Pages of publication: 3892
• a: 13.789 ± 0.0019 Å
• b: 13.8536 ± 0.0019 Å
• c: 18.622 ± 0.002 Å
• α: 86.151 ± 0.003°
• β: 85.941 ± 0.003°
• γ: 61.916 ± 0.002°
• Cell volume: 3128.3 ± 0.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1232
• Residual factor for significantly intense reflections: 0.0662
• Weighted residual factors for significantly intense reflections: 0.1697
• Weighted residual factors for all reflections included in the refinement: 0.2255
• Goodness-of-fit parameter for all reflections included in the refinement: 0.959
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No