Information card for entry 7013285

Structure parameters

• Formula: C61 H40 Cl2 Co4 O9 P4 Pd
• Calculated formula: C61 H40 Cl2 Co4 O9 P4 Pd
• SMILES: [Pd]12([Co]345([Co]67([P]([C]89[Co]%10([Co]8(C#[O])(C#[O])([C]=9%10[P]3(c3ccccc3)c3ccccc3)C#[O])([P]([C]46=[C]57[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])C#[O])(c1ccccc1)c1ccccc1)(C#[O])C#[O])(C2=O)C#[O])(Cl)Cl
• Title of publication: Synthesis and structural characterization of novel palladium complexes chelated by bulky cobalt-containing phosphine ligands: unusual palladium?cobalt bond formation
• Authors of publication: Hong, Fung-E; Chang, Chin-Pei; Chang, Yu-Chang
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 20
• Pages of publication: 3892
• a: 15.029 ± 0.004 Å
• b: 23.761 ± 0.007 Å
• c: 17.18 ± 0.005 Å
• α: 90°
• β: 98.846 ± 0.007°
• γ: 90°
• Cell volume: 6062 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.2518
• Residual factor for significantly intense reflections: 0.0889
• Weighted residual factors for significantly intense reflections: 0.2158
• Weighted residual factors for all reflections included in the refinement: 0.3144
• Goodness-of-fit parameter for all reflections included in the refinement: 0.986
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No