Information card for entry 7013629

Structure parameters

• Formula: C88 H72 Cl6 Ir4 N2 O10 P4 Sn2
• Calculated formula: C88 H60 Cl6 Ir4 N2 O10 P4 Sn2
• Title of publication: A coordinatively flexible ligand for carbonyl clusters: bridging and terminal SnCl3 groups in the iridium clusters [Ir4(CO)11(μ-SnCl3)]-, [Ir4(CO)10(SnCl3)(μ-SnCl3)]2- and [Ir6(CO)15(μ3-SnCl3)]-
• Authors of publication: Garlaschelli, Luigi; Greco, Francesco; Peli, Giulia; Manassero, Mario; Sansoni, Mirella; Pergola, Roberto Della
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 24
• Pages of publication: 4700 - 4703
• a: 11.096 ± 0.001 Å
• b: 15.007 ± 0.001 Å
• c: 27.976 ± 0.003 Å
• α: 104.69 ± 0.01°
• β: 93.39 ± 0.01°
• γ: 90.39 ± 0.01°
• Cell volume: 4497.2 ± 0.7 ų
• Cell temperature: 223 K
• Ambient diffraction temperature: 223 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.062
• Residual factor for significantly intense reflections: 0.062
• Weighted residual factors for significantly intense reflections: 0.079
• Goodness-of-fit parameter for all reflections: 0.948
• Goodness-of-fit parameter for significantly intense reflections: 0.948
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: Mo-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No