Information card for entry 7013630

Structure parameters

• Formula: C32 H22 Cl5 Ir6 N O15 Sn
• Calculated formula: C32 H20 Cl5 Ir6 N O15 Sn
• Title of publication: A coordinatively flexible ligand for carbonyl clusters: bridging and terminal SnCl3 groups in the iridium clusters [Ir4(CO)11(μ-SnCl3)]-, [Ir4(CO)10(SnCl3)(μ-SnCl3)]2- and [Ir6(CO)15(μ3-SnCl3)]-
• Authors of publication: Garlaschelli, Luigi; Greco, Francesco; Peli, Giulia; Manassero, Mario; Sansoni, Mirella; Pergola, Roberto Della
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 24
• Pages of publication: 4700 - 4703
• a: 10.321 ± 0.001 Å
• b: 15.465 ± 0.002 Å
• c: 15.482 ± 0.002 Å
• α: 85.64 ± 0.01°
• β: 81.15 ± 0.01°
• γ: 78.11 ± 0.01°
• Cell volume: 2386.8 ± 0.5 ų
• Cell temperature: 223 K
• Ambient diffraction temperature: 223 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.045
• Residual factor for significantly intense reflections: 0.045
• Weighted residual factors for significantly intense reflections: 0.071
• Goodness-of-fit parameter for all reflections: 0.994
• Goodness-of-fit parameter for significantly intense reflections: 0.994
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: Mo-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No