Information card for entry 7021008

Structure parameters

• Formula: C44 H104 Cl4 Cu4 N8 O Si4 Sn4
• Calculated formula: C44 H104 Cl4 Cu4 N8 O Si4 Sn4
• SMILES: [Sn]12([Cu]3([Sn]4(Cl)[N]([Cu][N]1([Si](N2C(C)(C)C)(C)C)C(C)(C)C)([Si](N4C(C)(C)C)(C)C)C(C)(C)C)[Sn]1(Cl)[N]2([Cu]4[Cu]([N]1([Si]2(C)C)C(C)(C)C)[N]1([Sn]3(Cl)[N]4([Si]1(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)Cl.O1CCCC1
• Title of publication: Heavier carbene analogues and their derivatives as κ-El, κ(2)-El,N, and κ(2)-N,N' ligands: different reactivity patterns for acyclic and cyclic diamidogermylenes and -stannylenes.
• Authors of publication: West, Joseph K.; Fondong, Gregory L.; Noll, Bruce C.; Stahl, Lothar
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 11
• Pages of publication: 3835 - 3842
• a: 15.051 ± 0.002 Å
• b: 21.782 ± 0.003 Å
• c: 25.431 ± 0.003 Å
• α: 108.904 ± 0.002°
• β: 98.938 ± 0.002°
• γ: 91.934 ± 0.002°
• Cell volume: 7760.2 ± 1.7 ų
• Cell temperature: 173.15 K
• Ambient diffraction temperature: 173.15 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0483
• Residual factor for significantly intense reflections: 0.039
• Weighted residual factors for significantly intense reflections: 0.1014
• Weighted residual factors for all reflections included in the refinement: 0.1054
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No