Information card for entry 7021648

Structure parameters

• Common name: lithium-bis(trimethylphosphineoxid-mu-trimethylphosphineoxide- mu-3,5-bis(trifluoromethyl)pyrazolate-bis(3,5- bis(trifluoromethyl)pyrazolate)cobalt(ii)
• Chemical name: lithium-bis(trimethylphosphineoxid-μ-trimethylphosphineoxide- μ-3,5-bis(trifluoromethyl)pyrazolate- bis(3,5-bis(trifluoromethyl)pyrazolate)cobalt(ii)
• Formula: C24 H30 Co F18 Li N6 O3 P3
• Calculated formula: C24 H30 Co F18 Li N6 O3 P3
• Title of publication: Synthesis and structures of Co bis-trifluoromethylpyrazolate complexes.
• Authors of publication: Rivers, Joseph H.; Jones, Richard A.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 36
• Pages of publication: 12898 - 12907
• a: 14.371 ± 0.003 Å
• b: 12.277 ± 0.003 Å
• c: 24.941 ± 0.008 Å
• α: 90°
• β: 115.58 ± 0.02°
• γ: 90°
• Cell volume: 3969.1 ± 1.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0783
• Residual factor for significantly intense reflections: 0.0678
• Weighted residual factors for significantly intense reflections: 0.1516
• Weighted residual factors for all reflections included in the refinement: 0.1584
• Goodness-of-fit parameter for all reflections included in the refinement: 1.202
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No