Information card for entry 7021813

Structure parameters

• Chemical name: [Rh(dibpe)Br(C6H5)]2[BArF4]2
• Formula: C57.13 H59.27 B Br Cl2.27 F24 P2 Rh
• Calculated formula: C57.135 H59.27 B Br Cl2.27 F24 P2 Rh
• Title of publication: C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4](-) at a Rh(i) centre in solution and the solid-state.
• Authors of publication: Pike, Sebastian D.; Weller, Andrew S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 36
• Pages of publication: 12832 - 12835
• a: 13.4344 ± 0.0004 Å
• b: 16.2486 ± 0.0005 Å
• c: 16.35 ± 0.0005 Å
• α: 73.8487 ± 0.0016°
• β: 88.5368 ± 0.0015°
• γ: 87.5505 ± 0.0011°
• Cell volume: 3424.7 ± 0.18 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0826
• Residual factor for significantly intense reflections: 0.0606
• Weighted residual factors for all reflections: 0.1498
• Weighted residual factors for significantly intense reflections: 0.1369
• Weighted residual factors for all reflections included in the refinement: 0.1498
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9485
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No