Information card for entry 7021814

Structure parameters

• Chemical name: [RhdibpeNBD][BArCl4]
• Formula: C49 H60 B Cl8 P2 Rh
• Calculated formula: C49 H60 B Cl8 P2 Rh
• Title of publication: C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4](-) at a Rh(i) centre in solution and the solid-state.
• Authors of publication: Pike, Sebastian D.; Weller, Andrew S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 36
• Pages of publication: 12832 - 12835
• a: 12.0494 ± 0.0003 Å
• b: 12.4222 ± 0.0003 Å
• c: 17.4694 ± 0.0004 Å
• α: 88.3937 ± 0.0009°
• β: 89.8872 ± 0.0009°
• γ: 86.3926 ± 0.0009°
• Cell volume: 2608.61 ± 0.11 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.087
• Residual factor for significantly intense reflections: 0.0628
• Weighted residual factors for all reflections: 0.1563
• Weighted residual factors for significantly intense reflections: 0.1454
• Weighted residual factors for all reflections included in the refinement: 0.1563
• Goodness-of-fit parameter for all reflections included in the refinement: 1.009
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No