Information card for entry 7021816

Structure parameters

• Chemical name: [Rh(dibpe)Cl{C6ClH3(B(ArCl)3)}]2
• Formula: C87.1 H110.2 B2 Cl22.2 P4 Rh2
• Calculated formula: C87.1028 H110.206 B2 Cl22.2056 P4 Rh2
• Title of publication: C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4](-) at a Rh(i) centre in solution and the solid-state.
• Authors of publication: Pike, Sebastian D.; Weller, Andrew S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 36
• Pages of publication: 12832 - 12835
• a: 13.2301 ± 0.0003 Å
• b: 17.4742 ± 0.0005 Å
• c: 23.2939 ± 0.0005 Å
• α: 78.048 ± 0.002°
• β: 88.4952 ± 0.0019°
• γ: 77.569 ± 0.002°
• Cell volume: 5144 ± 0.2 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0585
• Residual factor for significantly intense reflections: 0.0524
• Weighted residual factors for all reflections: 0.1381
• Weighted residual factors for significantly intense reflections: 0.1351
• Weighted residual factors for all reflections included in the refinement: 0.1381
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9822
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No