Information card for entry 7021815

Structure parameters

• Chemical name: Rh(dibpe)h6-BArCl4
• Formula: C42 H52 B Cl8 P2 Rh
• Calculated formula: C42 H52 B Cl8 P2 Rh
• Title of publication: C-Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4](-) at a Rh(i) centre in solution and the solid-state.
• Authors of publication: Pike, Sebastian D.; Weller, Andrew S.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 36
• Pages of publication: 12832 - 12835
• a: 12.6148 ± 0.0003 Å
• b: 12.7474 ± 0.0003 Å
• c: 16.1361 ± 0.0003 Å
• α: 101.97 ± 0.0018°
• β: 102.999 ± 0.0019°
• γ: 106.98 ± 0.002°
• Cell volume: 2311.91 ± 0.1 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0395
• Residual factor for significantly intense reflections: 0.0386
• Weighted residual factors for all reflections: 0.105
• Weighted residual factors for significantly intense reflections: 0.1039
• Weighted residual factors for all reflections included in the refinement: 0.105
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0037
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No