Information card for entry 7022723

Structure parameters

• Formula: C58 H50 Cl4 O P3 Rh Si
• Calculated formula: C58 H50 Cl4 O P3 Rh Si
• Title of publication: Si-C bond cleavage by hydride complexes of rhodium and iridium: comparison of Si-C(sp(2)) and Si-C(sp(3)) activation.
• Authors of publication: Kameo, Hajime; Ishii, Sho; Nakazawa, Hiroshi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2013
• Journal volume: 42
• Journal issue: 13
• Pages of publication: 4663 - 4669
• a: 12.0136 ± 0.0007 Å
• b: 12.8856 ± 0.0005 Å
• c: 17.6972 ± 0.0011 Å
• α: 94.38 ± 0.003°
• β: 105.563 ± 0.003°
• γ: 90.173 ± 0.002°
• Cell volume: 2630.6 ± 0.2 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0471
• Residual factor for significantly intense reflections: 0.0428
• Weighted residual factors for significantly intense reflections: 0.1037
• Weighted residual factors for all reflections included in the refinement: 0.1062
• Goodness-of-fit parameter for all reflections included in the refinement: 1.075
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No