Information card for entry 7028062

Structure parameters

• Chemical name: μ-propane-1,3-diyl-bis[bis(dimethylglyoximato-N,N')(triphenylpho sphine) rhodium(III)]
• Formula: C55 H64 N8 O8 P2 Rh2
• Calculated formula: C55 H64 N8 O8 P2 Rh2
• SMILES: CC1C(C)=N(=O)[Rh]2(CCC[Rh]34([N](=C(C(C)=N3=O)C)O)([N](=C(C(C)=N4=O)C)O)[P](c3ccccc3)(c3ccccc3)c3ccccc3)([N]=1O)([N](=C(C(C)=N2=O)C)O)[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Syntheses and structures of novel cyclic and dinuclear organorhodoximes: a homologous series of di- to penta-methylene-bridged complexes ‡
• Authors of publication: Steinborn, Dirk; Rausch, Mario; Bruhn, Clemens; Schmidt, Harry; Ströhl, Dieter
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 2
• Pages of publication: 221
• a: 12.405 ± 0.003 Å
• b: 15.004 ± 0.006 Å
• c: 16.292 ± 0.004 Å
• α: 108.61 ± 0.03°
• β: 98.53 ± 0.02°
• γ: 96.58 ± 0.03°
• Cell volume: 2799.3 ± 1.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0359
• Weighted residual factors for all reflections: 0.0923
• Weighted residual factors for significantly intense reflections: 0.0868
• Goodness-of-fit parameter for all reflections: 1.054
• Goodness-of-fit parameter for significantly intense reflections: 1.101
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No