Information card for entry 7028063

Structure parameters

• Chemical name: μ-butane-1,4-diyl-bis[bis(dimethylglyoximato-N,N')(triphenylphos phine) rhodium(III)]
• Formula: C62 H72 Cl18 N8 O8 P2 Rh2
• Calculated formula: C62 H72 Cl18 N8 O8 P2 Rh2
• SMILES: [P]([Rh]12(N(=C(C(=[N]1O)C)C)=O)([N](=C(C(C)=N2=O)C)O)CCCC[Rh]12([P](c3ccccc3)(c3ccccc3)c3ccccc3)(N(=C(C(C)=[N]1O)C)=O)[N](=C(C(C)=N2=O)C)O)(c1ccccc1)(c1ccccc1)c1ccccc1.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl
• Title of publication: Syntheses and structures of novel cyclic and dinuclear organorhodoximes: a homologous series of di- to penta-methylene-bridged complexes ‡
• Authors of publication: Steinborn, Dirk; Rausch, Mario; Bruhn, Clemens; Schmidt, Harry; Ströhl, Dieter
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 2
• Pages of publication: 221
• a: 9.127 ± 0.003 Å
• b: 14.238 ± 0.003 Å
• c: 18.729 ± 0.008 Å
• α: 111.9 ± 0.04°
• β: 93.02 ± 0.04°
• γ: 99.67 ± 0.03°
• Cell volume: 2208.3 ± 1.5 ų
• Cell temperature: 220 ± 1 K
• Ambient diffraction temperature: 220 ± 1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0931
• Residual factor for significantly intense reflections: 0.0857
• Weighted residual factors for all reflections: 0.2708
• Weighted residual factors for significantly intense reflections: 0.2617
• Goodness-of-fit parameter for all reflections: 1.128
• Goodness-of-fit parameter for significantly intense reflections: 1.171
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No