Information card for entry 7030937

Structure parameters

• Formula: C58 H70 N3 O2 P2 Si Sm
• Calculated formula: C58 H70 N3 O2 P2 Si Sm
• Title of publication: Differences in the cyclometalation reactivity of bisphosphinimine-supported organo-rare earth complexes.
• Authors of publication: Zamora, Matthew T.; Johnson, Kevin R. D.; Hänninen, Mikko M; Hayes, Paul G.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 28
• Pages of publication: 10739 - 10750
• a: 14.806 ± 0.002 Å
• b: 14.713 ± 0.002 Å
• c: 29.208 ± 0.005 Å
• α: 90°
• β: 101.263 ± 0.0018°
• γ: 90°
• Cell volume: 6240.2 ± 1.6 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0899
• Residual factor for significantly intense reflections: 0.0788
• Weighted residual factors for significantly intense reflections: 0.1761
• Weighted residual factors for all reflections included in the refinement: 0.1798
• Goodness-of-fit parameter for all reflections included in the refinement: 1.2
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No