Information card for entry 7045018

Structure parameters

• Formula: C72 H88 Cl Li2 Mn O12 Si4
• Calculated formula: C72 H88 Cl Li2 Mn O12 Si4
• Title of publication: High-yield synthesis of a unique Mn(iii) siloxide complex through KMnO₄ oxidation of a Mn(ii) precursor.
• Authors of publication: Lorenz, Volker; Ehle, Sophie; Liebing, Phil; Engelhardt, Felix; Hashemi-Haeri, Haleh; Oehler, Florian; Hinderberger, Dariush; Busse, Sabine; Urbaschok, Jens; Edelmann, Frank T.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• Journal volume: 47
• Journal issue: 1
• Pages of publication: 62 - 66
• a: 10.447 ± 0.003 Å
• b: 15.753 ± 0.004 Å
• c: 21.429 ± 0.004 Å
• α: 90°
• β: 101.33 ± 0.02°
• γ: 90°
• Cell volume: 3457.9 ± 1.5 ų
• Cell temperature: 100 ± 1 K
• Ambient diffraction temperature: 100 ± 1 K
• Number of distinct elements: 7
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 n 1
• Hall space group symbol: P -2yac
• Residual factor for all reflections: 0.0712
• Residual factor for significantly intense reflections: 0.0658
• Weighted residual factors for significantly intense reflections: 0.129
• Weighted residual factors for all reflections included in the refinement: 0.1314
• Goodness-of-fit parameter for all reflections included in the refinement: 1.24
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No