Information card for entry 7045019

Structure parameters

• Formula: C76 H96 Cl2 Li4 Mn O13 Si4
• Calculated formula: C75.996 H95.992 Cl2 Li4 Mn O12.999 Si4
• Title of publication: High-yield synthesis of a unique Mn(iii) siloxide complex through KMnO₄ oxidation of a Mn(ii) precursor.
• Authors of publication: Lorenz, Volker; Ehle, Sophie; Liebing, Phil; Engelhardt, Felix; Hashemi-Haeri, Haleh; Oehler, Florian; Hinderberger, Dariush; Busse, Sabine; Urbaschok, Jens; Edelmann, Frank T.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• Journal volume: 47
• Journal issue: 1
• Pages of publication: 62 - 66
• a: 13.5878 ± 0.0003 Å
• b: 42.7842 ± 0.0012 Å
• c: 13.6537 ± 0.0003 Å
• α: 90°
• β: 98.723 ± 0.002°
• γ: 90°
• Cell volume: 7845.7 ± 0.3 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0782
• Residual factor for significantly intense reflections: 0.0456
• Weighted residual factors for significantly intense reflections: 0.0985
• Weighted residual factors for all reflections included in the refinement: 0.1093
• Goodness-of-fit parameter for all reflections included in the refinement: 0.96
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No