Bismuth as a versatile cation for luminescence in coordination polymers from BiX<sub>3</sub>/4,4'-bipy: understanding of photophysics by quantum chemical calculations and structural parallels to lanthanides.
Authors of publication
Sorg, Jens R.; Wehner, Tobias; Matthes, Philipp R.; Sure, Rebecca; Grimme, Stefan; Heine, Johanna; Müller-Buschbaum, Klaus
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
23
Pages of publication
7669 - 7681
a
8.7574 ± 0.0007 Å
b
11.1147 ± 0.0009 Å
c
14.6158 ± 0.0012 Å
α
82.744 ± 0.001°
β
78.574 ± 0.001°
γ
70.628 ± 0.001°
Cell volume
1312.67 ± 0.18 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0405
Residual factor for significantly intense reflections
0.0345
Weighted residual factors for significantly intense reflections
0.0966
Weighted residual factors for all reflections included in the refinement
0.1057
Goodness-of-fit parameter for all reflections included in the refinement
