Bismuth as a versatile cation for luminescence in coordination polymers from BiX<sub>3</sub>/4,4'-bipy: understanding of photophysics by quantum chemical calculations and structural parallels to lanthanides.
Authors of publication
Sorg, Jens R.; Wehner, Tobias; Matthes, Philipp R.; Sure, Rebecca; Grimme, Stefan; Heine, Johanna; Müller-Buschbaum, Klaus
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
23
Pages of publication
7669 - 7681
a
13.062 ± 0.003 Å
b
12.287 ± 0.002 Å
c
8.1125 ± 0.0015 Å
α
90°
β
121.421 ± 0.005°
γ
90°
Cell volume
1111.1 ± 0.4 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
5
Space group number
12
Hermann-Mauguin space group symbol
C 1 2/m 1
Hall space group symbol
-C 2y
Residual factor for all reflections
0.0225
Residual factor for significantly intense reflections
0.0223
Weighted residual factors for significantly intense reflections
0.0552
Weighted residual factors for all reflections included in the refinement
0.0554
Goodness-of-fit parameter for all reflections included in the refinement
