Information card for entry 7047228

Structure parameters

• Formula: C63 H86 Ge N6 O27 Rh12
• Calculated formula: C63 H86 Ge N6 O27 Rh12
• Title of publication: Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [Rh13Ge(CO)25]3-, [Rh14Ge2(CO)30]2- and [Rh12Ge(CO)27]4- cluster anions.
• Authors of publication: Boccalini, Alberto; Dyson, Paul; Femoni, Cristina; Iapalucci, Maria Carmela; Ruggieri, Silvia; Zacchini, Stefano
• Journal of publication: Dalton Transactions
• Year of publication: 2018
• a: 13.279 ± 0.003 Å
• b: 26.614 ± 0.005 Å
• c: 27.049 ± 0.005 Å
• α: 119.285 ± 0.003°
• β: 98.012 ± 0.004°
• γ: 95.078 ± 0.004°
• Cell volume: 8119 ± 3 ų
• Cell temperature: 77 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0784
• Residual factor for significantly intense reflections: 0.0726
• Weighted residual factors for significantly intense reflections: 0.2044
• Weighted residual factors for all reflections included in the refinement: 0.2114
• Goodness-of-fit parameter for all reflections included in the refinement: 1.088
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No