Information card for entry 7052342

Structure parameters

• Formula: C86 H92 Cl2 F20 N4 O2 P4 Ru2 Sb2
• Calculated formula: C86 H92 Cl2 F20 N4 O2 P4 Ru2 Sb2
• SMILES: C1CC[C@@H]2[P@]1(c1ccccc1)[Ru]13456([c]7([cH]1[cH]3[c]4(C)[cH]5[cH]67)C(C)C)(Cl)[N]#Cc1c(F)c(F)c(N=P([C@H]3CCC[P@]3(c3ccccc3)[Ru]34567([N]#Cc8c(F)c(F)c(N=P2(c2ccccc2)c2ccccc2)c(F)c8F)([c]2([cH]3[cH]4[c]5(C)[cH]6[cH]72)C(C)C)Cl)(c2ccccc2)c2ccccc2)c(F)c1F.F[Sb](F)(F)(F)(F)[F-].O(CC)CC.F[Sb](F)(F)(F)(F)[F-].O(CC)CC
• Title of publication: Imination reactions of free and coordinated 2-diphenylphosphino-1-phenyl-phospholane: Access to regioisomeric ruthenium(<small>II</small>) complexes containing novel iminophosphorane‒phosphine ligands
• Authors of publication: Alba E. Díaz-Álvarez; Pascale Crochet; Maria Zablocka; Victorio Cadierno; Carine Duhayon; José Gimeno; Jean-Pierre Majoral
• Journal of publication: New Journal of Chemistry
• Year of publication: 2006
• Journal volume: 30
• Journal issue: 9
• Pages of publication: 1295
• a: 15.457 ± 0.001 Å
• b: 14.693 ± 0.0008 Å
• c: 20.184 ± 0.0011 Å
• α: 90°
• β: 99.75 ± 0.005°
• γ: 90°
• Cell volume: 4517.8 ± 0.5 ų
• Cell temperature: 180 K
• Ambient diffraction temperature: 180 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1657
• Residual factor for significantly intense reflections: 0.0637
• Weighted residual factors for all reflections: 0.0828
• Weighted residual factors for significantly intense reflections: 0.0675
• Weighted residual factors for all reflections included in the refinement: 0.0675
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1485
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No