Information card for entry 7103968

Structure parameters

• Common name: (CGC)phosphium arsenium tetrachloride
• Chemical name: t-butyl(dimetyl(tetra-methylcyclopentadienyl)silyl)amido arsenium aluminum tetrachloride
• Formula: C15 H27 Al As Cl4 N Si
• Calculated formula: C15 H27 Al As Cl4 N Si
• SMILES: C12(C(=C(C(=C1[As]=[N+](C(C)(C)C)[Si]2(C)C)C)C)C)C.[Al](Cl)(Cl)(Cl)[Cl-]
• Title of publication: The contrasting behaviour of bridged amido-cyclopentadienyl (constrained geometry) group 15 chlorides and cations derived therefrom
• Authors of publication: Wiacek, Robert J.; Macdonald, Charles L. B.; Jones, Jamie N.; Pietryga, Jeffrey M.; Cowley, Alan H.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 3
• Pages of publication: 430 - 431
• a: 18.184 ± 0.004 Å
• b: 8.2774 ± 0.0017 Å
• c: 30.284 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4558.2 ± 1.6 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for all reflections: 0.0918
• Residual factor for significantly intense reflections: 0.0678
• Weighted residual factors for significantly intense reflections: 0.1544
• Weighted residual factors for all reflections included in the refinement: 0.172
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No