Information card for entry 7103969

Structure parameters

• Common name: (CGC)phosphium stibocenium tetrachloride
• Chemical name: t-butyl(dimetyl(tetra-methylcyclopentadienyl)silyl)amido stibocenium aluminum tetrachloride
• Formula: C15 H27 Al Cl4 N Sb Si
• Calculated formula: C15 H27 Al Cl4 N Sb Si
• SMILES: [Sb]123N(C(C)(C)C)[Si]([c]53[c]1(C)c(c([c]25C)C)C)(C)C.[Cl-][Al](Cl)(Cl)Cl
• Title of publication: The contrasting behaviour of bridged amido-cyclopentadienyl (constrained geometry) group 15 chlorides and cations derived therefrom
• Authors of publication: Wiacek, Robert J.; Macdonald, Charles L. B.; Jones, Jamie N.; Pietryga, Jeffrey M.; Cowley, Alan H.
• Journal of publication: Chemical Communications (Cambridge, United Kingdom)
• Year of publication: 2003
• Journal issue: 3
• Pages of publication: 430 - 431
• a: 10.064 ± 0.005 Å
• b: 11.154 ± 0.005 Å
• c: 12.12 ± 0.005 Å
• α: 92.411 ± 0.005°
• β: 114.403 ± 0.005°
• γ: 110.722 ± 0.005°
• Cell volume: 1130.2 ± 0.9 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.024
• Residual factor for significantly intense reflections: 0.0202
• Weighted residual factors for significantly intense reflections: 0.0431
• Weighted residual factors for all reflections included in the refinement: 0.0443
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No