Information card for entry 7110916

Structure parameters

• Formula: C67.5 H60 Cl3 F6 Ir N6 O2 P3 Rh
• Calculated formula: C67.5 H60 Cl3 F6 Ir N6 O2 P3 Rh
• Title of publication: Redox-active heterobinuclear triazenide-bridged complexes; ancillary ligand control of electron distribution in a three-electron metal‒metal bond
• Authors of publication: Connelly, Neil G.; Hayward, Owen D.; Klangsinsirikul, Phimphaka; Orpen, A. Guy; Rieger, Philip H.
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 11
• Pages of publication: 963
• a: 12.967 ± 0.003 Å
• b: 13.714 ± 0.002 Å
• c: 19.83 ± 0.003 Å
• α: 97.712 ± 0.012°
• β: 98.499 ± 0.019°
• γ: 90.43 ± 0.012°
• Cell volume: 3454.7 ± 1.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1494
• Residual factor for significantly intense reflections: 0.064
• Weighted residual factors for significantly intense reflections: 0.1123
• Weighted residual factors for all reflections included in the refinement: 0.1431
• Goodness-of-fit parameter for all reflections included in the refinement: 0.944
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No