Information card for entry 7110915

Structure parameters

• Formula: C69 H62 Cl6 Ir N6 O2 P2 Rh
• Calculated formula: C69 H62 Cl6 Ir N6 O2 P2 Rh
• Title of publication: Redox-active heterobinuclear triazenide-bridged complexes; ancillary ligand control of electron distribution in a three-electron metal‒metal bond
• Authors of publication: Connelly, Neil G.; Hayward, Owen D.; Klangsinsirikul, Phimphaka; Orpen, A. Guy; Rieger, Philip H.
• Journal of publication: Chemical Communications
• Year of publication: 2000
• Journal issue: 11
• Pages of publication: 963
• a: 12.9339 ± 0.001 Å
• b: 15.1205 ± 0.0013 Å
• c: 18.301 ± 0.003 Å
• α: 83.5 ± 0.08°
• β: 71.74 ± 0.06°
• γ: 88.57 ± 0.07°
• Cell volume: 3376.8 ± 1.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0438
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.075
• Weighted residual factors for all reflections included in the refinement: 0.0794
• Goodness-of-fit parameter for all reflections included in the refinement: 0.986
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No