Information card for entry 7117028

Structure parameters

• Common name: (PPh4)[Ge(N3)3]
• Chemical name: (PPh4)[Ge(N3)3]
• Formula: C24 H20 Ge N9 P
• Calculated formula: C24 H20 Ge N9 P
• SMILES: [Ge](N=N#N)(N=N#N)N=N#N.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Homoleptic low-valent polyazides of group 14 elements
• Authors of publication: Benjamin Peerless; Theo Keane; Anthony J. H. M. Meijer; Peter Portius
• Journal of publication: Chem.Commun.
• Year of publication: 2015
• Journal volume: 51
• Pages of publication: 7435
• a: 7.7712 ± 0.0002 Å
• b: 11.4711 ± 0.0004 Å
• c: 14.2003 ± 0.0004 Å
• α: 93.278 ± 0.002°
• β: 99.357 ± 0.002°
• γ: 100.865 ± 0.002°
• Cell volume: 1221.59 ± 0.06 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0645
• Residual factor for significantly intense reflections: 0.0376
• Weighted residual factors for significantly intense reflections: 0.0731
• Weighted residual factors for all reflections included in the refinement: 0.0807
• Goodness-of-fit parameter for all reflections included in the refinement: 1.09
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No