Information card for entry 7119224

Structure parameters

• Formula: C30 H44 Co2 Ge N2 O6 P2
• Calculated formula: C30 H44 Co2 Ge N2 O6 P2
• SMILES: [Ge]123[Co]([P](C(C)(C)C)(CN3c3ccccc3N2C[P]([Co]1(C#[O])(C#[O])C#[O])(C(C)(C)C)C(C)(C)C)C(C)(C)C)(C#[O])(C#[O])C#[O]
• Title of publication: Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.
• Authors of publication: Álvarez-Rodríguez, Lucía; Brugos, Javier; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Polo, Diego
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2017
• Journal volume: 53
• Journal issue: 5
• Pages of publication: 893 - 896
• a: 17.2945 ± 0.0014 Å
• b: 17.5482 ± 0.0008 Å
• c: 22.8262 ± 0.0009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6927.5 ± 0.7 ų
• Cell temperature: 145 ± 2 K
• Ambient diffraction temperature: 145 ± 2 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1414
• Residual factor for significantly intense reflections: 0.0934
• Weighted residual factors for significantly intense reflections: 0.2533
• Weighted residual factors for all reflections included in the refinement: 0.3534
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No