Information card for entry 7122053

Structure parameters

• Formula: C43 H73 Cl N5 Ni O3.5 Si2
• Calculated formula: C43 H73 Cl N5 Ni O3.5 Si2
• Title of publication: Metal nitrene-like reactivity of a Si[double bond, length as m-dash]N bond towards CO₂.
• Authors of publication: Hadlington, Terrance J.; Szilvási, Tibor; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 67
• Pages of publication: 9352 - 9355
• a: 32.1007 ± 0.0004 Å
• b: 12.451 ± 0.0002 Å
• c: 25.1623 ± 0.0004 Å
• α: 90°
• β: 99.965 ± 0.002°
• γ: 90°
• Cell volume: 9905.3 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0598
• Residual factor for significantly intense reflections: 0.049
• Weighted residual factors for significantly intense reflections: 0.1324
• Weighted residual factors for all reflections included in the refinement: 0.1441
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No