Information card for entry 7122054

Structure parameters

• Formula: C44 H77 Cl N6 Ni O2 Si2
• Calculated formula: C44 H77 Cl N6 Ni O2 Si2
• Title of publication: Metal nitrene-like reactivity of a Si[double bond, length as m-dash]N bond towards CO₂.
• Authors of publication: Hadlington, Terrance J.; Szilvási, Tibor; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 67
• Pages of publication: 9352 - 9355
• a: 11.2566 ± 0.0005 Å
• b: 12.7269 ± 0.0006 Å
• c: 17.1548 ± 0.0007 Å
• α: 89.747 ± 0.004°
• β: 85.046 ± 0.003°
• γ: 86.16 ± 0.004°
• Cell volume: 2442.94 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0535
• Residual factor for significantly intense reflections: 0.0424
• Weighted residual factors for significantly intense reflections: 0.1125
• Weighted residual factors for all reflections included in the refinement: 0.1241
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No