Information card for entry 7134540

Structure parameters

• Formula: C28 H77.19 Mo4 N4 O64.59 P8 V4
• Calculated formula: C28 H77.1804 Mo4 N4 O64.5922 P8 V4
• Title of publication: A mixed metallic and mixed valence MoV4VIV2VIII2 complex as an electron transfer photo-catalyst for the hydrogen evolution reaction
• Authors of publication: Morla, Kalyankumar S.; Thakre, Dewendra; Mourya, Adarsh K.; Singh, Piyush; Karnamkkott, Harsha S.; Ahamed, Subuhan; Sahoo, Subham; Bhattacharya, Ishita; Banerjee, Siddhartha; Sarma, Debajit; Mondal, Kartik Chandra; Ghosh, Sujit Kumar; Wankhade, Atul V.; Banerjee, Abhishek
• Journal of publication: Chemical Communications
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 49
• Pages of publication: 8919 - 8922
• a: 17.3825 ± 0.0004 Å
• b: 14.0926 ± 0.0003 Å
• c: 16.5564 ± 0.0004 Å
• α: 90°
• β: 107.986 ± 0.001°
• γ: 90°
• Cell volume: 3857.54 ± 0.15 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 12
• Hermann-Mauguin space group symbol: C 1 2/m 1
• Hall space group symbol: -C 2y
• Residual factor for all reflections: 0.0417
• Residual factor for significantly intense reflections: 0.0406
• Weighted residual factors for significantly intense reflections: 0.1041
• Weighted residual factors for all reflections included in the refinement: 0.105
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No