Information card for entry 7134541

Structure parameters

• Formula: C14 H46 Mo4 N2 O42 P4 V
• Calculated formula: C14 H46 Mo4 N2 O42 P4 V
• Title of publication: A mixed metallic and mixed valence MoV4VIV2VIII2 complex as an electron transfer photo-catalyst for the hydrogen evolution reaction
• Authors of publication: Morla, Kalyankumar S.; Thakre, Dewendra; Mourya, Adarsh K.; Singh, Piyush; Karnamkkott, Harsha S.; Ahamed, Subuhan; Sahoo, Subham; Bhattacharya, Ishita; Banerjee, Siddhartha; Sarma, Debajit; Mondal, Kartik Chandra; Ghosh, Sujit Kumar; Wankhade, Atul V.; Banerjee, Abhishek
• Journal of publication: Chemical Communications
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 49
• Pages of publication: 8919 - 8922
• a: 12.4325 ± 0.0004 Å
• b: 10.9812 ± 0.0004 Å
• c: 17.2749 ± 0.0006 Å
• α: 90°
• β: 99.879 ± 0.001°
• γ: 90°
• Cell volume: 2323.46 ± 0.14 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.041
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for significantly intense reflections: 0.101
• Weighted residual factors for all reflections included in the refinement: 0.1021
• Goodness-of-fit parameter for all reflections included in the refinement: 1.079
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No