Information card for entry 7134548

Structure parameters

• Formula: C55 H85 B10 Cl0 Cu N6 Si3
• Calculated formula: C55 H85 B10 Cu N6 Si3
• Title of publication: Unprecedented bis(silylene)-supported silylone–metal complexes with Si0→ CuI, Si0→ NiI, and Si0→ NiII dative bonds
• Authors of publication: Shan, Changkai; Dai, Chenshu; Yao, Shenglai; Zhu, Jun; Driess, Matthias
• Journal of publication: Chemical Communications
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 49
• Pages of publication: 8875 - 8878
• a: 13.9122 ± 0.0006 Å
• b: 14.0705 ± 0.0007 Å
• c: 19.039 ± 0.0009 Å
• α: 105.727 ± 0.004°
• β: 99.055 ± 0.004°
• γ: 103.428 ± 0.004°
• Cell volume: 3391.3 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150.15 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0844
• Residual factor for significantly intense reflections: 0.0524
• Weighted residual factors for significantly intense reflections: 0.1183
• Weighted residual factors for all reflections included in the refinement: 0.1368
• Goodness-of-fit parameter for all reflections included in the refinement: 0.976
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No