Information card for entry 7134549

Structure parameters

• Chemical name: NacNacCu-CO
• Formula: C24 H29 Cu N2 O
• Calculated formula: C24 H29 Cu N2 O
• Title of publication: Unprecedented bis(silylene)-supported silylone–metal complexes with Si0→ CuI, Si0→ NiI, and Si0→ NiII dative bonds
• Authors of publication: Shan, Changkai; Dai, Chenshu; Yao, Shenglai; Zhu, Jun; Driess, Matthias
• Journal of publication: Chemical Communications
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 49
• Pages of publication: 8875 - 8878
• a: 8.6854 ± 0.0003 Å
• b: 9.9657 ± 0.0003 Å
• c: 13.5329 ± 0.0005 Å
• α: 70.233 ± 0.003°
• β: 83.025 ± 0.003°
• γ: 79.949 ± 0.003°
• Cell volume: 1082.95 ± 0.07 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.044
• Residual factor for significantly intense reflections: 0.0428
• Weighted residual factors for significantly intense reflections: 0.123
• Weighted residual factors for all reflections included in the refinement: 0.1239
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No