Information card for entry 7134551

Structure parameters

• Chemical name: CBSiNiBArF
• Formula: C65 H67 B10 F24 N4 Ni O Si3
• Calculated formula: C64.6667 H79.3333 B7.33333 F16 N4 Ni0.666667 O0.666667 Si2
• Title of publication: Unprecedented bis(silylene)-supported silylone–metal complexes with Si0→ CuI, Si0→ NiI, and Si0→ NiII dative bonds
• Authors of publication: Shan, Changkai; Dai, Chenshu; Yao, Shenglai; Zhu, Jun; Driess, Matthias
• Journal of publication: Chemical Communications
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 49
• Pages of publication: 8875 - 8878
• a: 16.2051 ± 0.001 Å
• b: 18.1741 ± 0.001 Å
• c: 19.452 ± 0.0013 Å
• α: 102.73 ± 0.005°
• β: 97.912 ± 0.005°
• γ: 104.587 ± 0.005°
• Cell volume: 5293.5 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1761
• Residual factor for significantly intense reflections: 0.1095
• Weighted residual factors for significantly intense reflections: 0.2659
• Weighted residual factors for all reflections included in the refinement: 0.3384
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No