Crystallography Open Database

Information card for entry 7134550

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Coordinates	7134550.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C75 H113 B10 N6 Ni Si3
Calculated formula	C75 H113 B10 N6 Ni Si3
Title of publication	Unprecedented bis(silylene)-supported silylone–metal complexes with Si0→ CuI, Si0→ NiI, and Si0→ NiII dative bonds
Authors of publication	Shan, Changkai; Dai, Chenshu; Yao, Shenglai; Zhu, Jun; Driess, Matthias
Journal of publication	Chemical Communications
Year of publication	2025
Journal volume	61
Journal issue	49
Pages of publication	8875 - 8878
a	20.2917 ± 0.0004 Å
b	15.5689 ± 0.0002 Å
c	25.7309 ± 0.0004 Å
α	90°
β	106.87 ± 0.002°
γ	90°
Cell volume	7779.1 ± 0.2 Å³
Cell temperature	150 ± 2 K
Ambient diffraction temperature	150 K
Number of distinct elements	6
Space group number	15
Hermann-Mauguin space group symbol	C 1 2/c 1
Hall space group symbol	-C 2yc
Residual factor for all reflections	0.057
Residual factor for significantly intense reflections	0.047
Weighted residual factors for significantly intense reflections	0.1231
Weighted residual factors for all reflections included in the refinement	0.1329
Goodness-of-fit parameter for all reflections included in the refinement	1.053
Diffraction radiation wavelength	1.54184 Å
Diffraction radiation type	CuKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

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