Information card for entry 7700121

Structure parameters

• Formula: C55 H59 N P2 Si2 Zn
• Calculated formula: C55 H59 N P2 Si2 Zn
• Title of publication: Reactivity of the carbodiphosphorane, (Ph₃P)₂C, towards main group metal alkyl compounds: coordination and cyclometalation.
• Authors of publication: Quinlivan, Patrick J.; Shlian, Daniel G.; Amemiya, Erika; Parkin, Gerard
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 25
• Pages of publication: 9139 - 9151
• a: 12.8053 ± 0.0019 Å
• b: 22.212 ± 0.003 Å
• c: 18.064 ± 0.003 Å
• α: 90°
• β: 105.577 ± 0.002°
• γ: 90°
• Cell volume: 4949.3 ± 1.3 ų
• Cell temperature: 230 ± 2 K
• Ambient diffraction temperature: 230 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1598
• Residual factor for significantly intense reflections: 0.059
• Weighted residual factors for significantly intense reflections: 0.1105
• Weighted residual factors for all reflections included in the refinement: 0.141
• Goodness-of-fit parameter for all reflections included in the refinement: 0.992
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No