Information card for entry 7719121

Structure parameters

• Formula: C66 H149 Ce2 N3 O20 Si5
• Calculated formula: C66 H149 Ce2 N3 O20 Si5
• Title of publication: Stepwise azido transfer to cerous tris(<i>tert</i>-butoxy)siloxide <i>via</i> trans-silylation with Me₃SiN₃.
• Authors of publication: Friedrich, Jochen; Riedmaier, Jonas; Maichle-Mössmer, Cäcilia; Anwander, Reiner
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 32
• Pages of publication: 12141 - 12144
• a: 14.2054 ± 0.0009 Å
• b: 25.3201 ± 0.0016 Å
• c: 26.965 ± 0.0015 Å
• α: 106.406 ± 0.002°
• β: 94.011 ± 0.002°
• γ: 100.8 ± 0.002°
• Cell volume: 9061.1 ± 1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1327
• Residual factor for significantly intense reflections: 0.0609
• Weighted residual factors for significantly intense reflections: 0.1091
• Weighted residual factors for all reflections included in the refinement: 0.1348
• Goodness-of-fit parameter for all reflections included in the refinement: 0.988
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No