Information card for entry 7721000

Structure parameters

• Formula: C42 H49 B9 P Rh
• Calculated formula: C42 H49 B9 P Rh
• Title of publication: Rhodacarborane complexes with a triphenylphosphonium substituent as efficient catalysts for on-water transfer hydrogenation of carbonyl compounds
• Authors of publication: Vinogradov, Mikhail M.; Nelubina, Yulia V.; Godovikov, Ivan A.; Godovikova, Maria I.; Kharitonov, Vladimir B.; Podyacheva, Evgeniya S.; Rodionov, Alexey
• Journal of publication: Dalton Transactions
• Year of publication: 2026
• a: 12.2842 ± 0.0002 Å
• b: 12.8919 ± 0.0002 Å
• c: 13.3696 ± 0.0002 Å
• α: 104.905 ± 0.001°
• β: 109.655 ± 0.001°
• γ: 95.244 ± 0.001°
• Cell volume: 1889.67 ± 0.05 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0388
• Residual factor for significantly intense reflections: 0.0313
• Weighted residual factors for significantly intense reflections: 0.0648
• Weighted residual factors for all reflections included in the refinement: 0.0686
• Goodness-of-fit parameter for all reflections included in the refinement: 1.01
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No