Information card for entry 7721001

Structure parameters

• Formula: C42 H49 B9 P Rh
• Calculated formula: C42 H49 B9 P Rh
• Title of publication: Rhodacarborane complexes with a triphenylphosphonium substituent as efficient catalysts for on-water transfer hydrogenation of carbonyl compounds
• Authors of publication: Vinogradov, Mikhail M.; Nelubina, Yulia V.; Godovikov, Ivan A.; Godovikova, Maria I.; Kharitonov, Vladimir B.; Podyacheva, Evgeniya S.; Rodionov, Alexey
• Journal of publication: Dalton Transactions
• Year of publication: 2026
• a: 10.5003 ± 0.0002 Å
• b: 19.699 ± 0.0003 Å
• c: 36.9753 ± 0.0005 Å
• α: 90°
• β: 92.319 ± 0.001°
• γ: 90°
• Cell volume: 7641.9 ± 0.2 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0579
• Residual factor for significantly intense reflections: 0.0385
• Weighted residual factors for significantly intense reflections: 0.0749
• Weighted residual factors for all reflections included in the refinement: 0.0823
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No