Information card for entry 8100881

Structure parameters

• Formula: C33 H56 B F4 P2 Rh
• Calculated formula: C33 H56 B F4 P2 Rh
• SMILES: [Rh]1234([P](CC[P]1(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1)[CH]1=[CH]2C2[CH]3=[CH]4C1C2.[B](F)(F)(F)[F-]
• Title of publication: Crystal structure of 1,2-bis(dicyclohexylphosphino)-ethane rhodium (I)-norborna-2,5-diene tetrafluoroborate, C~33~H~56~BF~4~P~2~Rh and of 1,2-bis(dicyclohexylphosphino)-ethane rhodium(I)-(Z,Z)-cycloocta- 1,5-diene tetrafluoroborate, C~34~H~60~BF~4~P~2~Rh · 1/2CH~3~OH
• Authors of publication: Kempe, Rhett; Spannenberg, Anke; Drexler, Hans-Joachim; Heller, Detlef
• Journal of publication: Zeitschrift für Kristallographie - New Crystal Structures
• Year of publication: 2001
• Journal volume: 216
• Journal issue: 1
• Pages of publication: 165 - 168
• a: 18.829 ± 0.004 Å
• b: 10.142 ± 0.002 Å
• c: 17.411 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3324.9 ± 1.1 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for significantly intense reflections: 0.033
• Weighted residual factors for significantly intense reflections: 0.0836
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No