Information card for entry 8100882

Structure parameters

• Formula: C34.5 H62 B F4 O0.5 P2 Rh
• Calculated formula: C34.5 H62 B F4 O0.5 P2 Rh
• Title of publication: Crystal structure of 1,2-bis(dicyclohexylphosphino)-ethane rhodium (I)-norborna-2,5-diene tetrafluoroborate, C~33~H~56~BF~4~P~2~Rh and of 1,2-bis(dicyclohexylphosphino)-ethane rhodium(I)-(Z,Z)-cycloocta- 1,5-diene tetrafluoroborate, C~34~H~60~BF~4~P~2~Rh · 1/2CH~3~OH
• Authors of publication: Kempe, Rhett; Spannenberg, Anke; Drexler, Hans-Joachim; Heller, Detlef
• Journal of publication: Zeitschrift für Kristallographie - New Crystal Structures
• Year of publication: 2001
• Journal volume: 216
• Journal issue: 1
• Pages of publication: 165 - 168
• a: 20.009 ± 0.004 Å
• b: 10.335 ± 0.002 Å
• c: 19.638 ± 0.004 Å
• α: 90°
• β: 114.51 ± 0.03°
• γ: 90°
• Cell volume: 3695.1 ± 1.3 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0463
• Weighted residual factors for significantly intense reflections: 0.1129
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No