Information card for entry 1100216

Structure parameters

• Chemical name: tetrakis(μ~3~-Trimethylphosphoraneiminato)-tris(trifluoromethanesulfonato-O,O')-(trifluoromethanesulfonato-O)-tetra-nickel(II)
• Formula: C16 H36 F12 N4 Ni4 O12 P4 S4
• Calculated formula: C16 H36 F15 N4 Ni4 O14 P4 S4
• Title of publication: Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
• Authors of publication: Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt
• Journal of publication: Zeitschrift fuer Anorganische und Allgemeine Chemie
• Year of publication: 2001
• Journal volume: 627
• Journal issue: 4
• Pages of publication: 747 - 754
• a: 15.6666 ± 0.0015 Å
• b: 14.7993 ± 0.001 Å
• c: 19.6063 ± 0.0018 Å
• α: 90°
• β: 105.908 ± 0.009°
• γ: 90°
• Cell volume: 4371.72 ų
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 4.43
• Weighted residual factors for significantly intense reflections: 4.43
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No