Information card for entry 1100217

Structure parameters

• Chemical name: Dibromo-bis(tris(dimethylamino)phosphaneimine)-nickel(ii)
• Formula: C12 H38 Br2 N8 Ni P2
• Calculated formula: C24 H76 Br4 N16 Ni P4
• Title of publication: Phosphaniminato- und Phosphanimin-Komplexe von Nickel(II). Die Kristallstrukturen von [Ni(O~3~SCF~3~)(NPMe~3~)]~4~, [Ni~4~Br~5~{NP(NMe~2~)~3~}~3~], [NiBr~2~{HNP(NMe~2~)~3~}~2~] und [Ni(PMePh~2~)~4~]
• Authors of publication: Krieger, Matthias; Gould, Robert O.; Harms, Klaus; Greiner, Andreas; Dehnicke, Kurt
• Journal of publication: Zeitschrift fuer Anorganische und Allgemeine Chemie
• Year of publication: 2001
• Journal volume: 627
• Journal issue: 4
• Pages of publication: 747 - 754
• a: 18.407 ± 0.001 Å
• b: 8.101 ± 0.001 Å
• c: 16.072 ± 0.002 Å
• α: 90°
• β: 94.74 ± 0.01°
• γ: 90°
• Cell volume: 2388.38 ų
• Ambient diffraction temperature: 203 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for significantly intense reflections: 3.4
• Weighted residual factors for significantly intense reflections: 3.4
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No